- The reduction in degree or intensity of
- Not biotic; not formed by biologic
viscosity - A measure of a fluid's resistance to tangential or shear stress.
Also referred to as dynamic viscosity; see also viscosity. Units are usually given in
Absorption - The penetration of atoms, ions, or molecules into the bulk
mass of a substance.
Actinomycetes - Any of numerous, generally filamentous, and often pathogenic,
microorganisms resembling both bacteria and fungi.
Adsorption -The retention of atoms, ions, or molecules onto the surface of
- the process of transfer of fluids (vapors or liquid) through a
geologic formation in response to a pressure gradient that may be caused by changes in barometric pressure,
water table levels, wind fluctuations, or infiltration.
-The process of bringing air into contact with a liquid (typically
water), usually by bubbling air through the liquid, spraying the liquid into the air, allowing the liquid to
cascade down a waterfall, or by mechanical agitation. Aeration serves to (1) strip dissolved gases from
solution, and/or (2) oxygenate the liquid. The rate at which a gas transfers into solution can be described
by Fick's First Law.
- Able to live, grow, or take place only when free oxygen is
An off-gas posttreatment unit for control of organic compounds by
thermal oxidation. A typical afterburner is a refractory-lined shell providing enough residence time at a
sufficiently high temperature to destroy organic compounds in the off-gas
- coarse mineral material (e.g., sand, gravel) that is mixed with either
cement to form concrete or tarry hydrocarbons to form asphalt.
Algae - chiefly aquatic, eucaryotic one-celled or multicellular plants
without true stems, roots and leaves, that are typically autotrophic, photosynthetic, and contain
chlorophyll. Algae are not typically found in groundwater.
- of or pertaining to a broad category of carbon compounds
distinguished by a straight, or branched, open chain arrangement of the constituent carbon atoms. The
carbon-carbon bonds may be either saturated or unsaturated. Alkanes, alkenes, and alkynes are aliphatic
- the homologous group of linear saturated aliphatic
hydrocarbons having the general formula C(n)H(2n+2). Alkanes can be straight chains, branched chains, or ring
structures. Also referred to as paraffins.
- the group of unsaturated hydrocarbons having the general
formula C(n)H(2n) and characterized by being highly chemically reactive. Also referred to as
- the group of unsaturated hydrocarbons with a triple
Carbon-Carbon bond having the general formula C(n)H(2n-2).
- surrounding; the surrounding environment and
- able to live, grow, or take place where free oxygen is not
Analog - in chemistry, a structural derivative of a parent
- the condition in which hydraulic properties of an aquifer
are not equal when measured in all directions.
- total deprivation of
- the extent to which a compound will dissolve in water. The
log of solubility is generally inversely related to molecular weight.
Aquifer - a geologic formation capable of transmitting significant
quantities of groundwater under normal hydraulic gradients.
- a geologic formation that may contain groundwater but is not
capable of transmitting significant quantities of groundwater under normal hydraulic gradients. In some
situations aquitards may function as confining beds.
- of or relating to organic compounds that resemble benzene
in chemical behavior. These compounds are unsaturated and characterized by containing at least one 6-carbon
- a line that is considered to be the limit to a curve. As
the curve approaches the asymptote, the distance separating the curve and the asymptote continues to
decrease, but the curve never actually intersects the asymptote.
- the reduction or lessening in amount
(e.g., a reduction in the
amount of contaminants in a plume as it migrates away from the source).
- the moisture contents which define a soil's liquid limit,
plastic limit, and sticky limit.
Auger - a tool for drilling/boring into unconsolidated earth materials
(soil) consisting of a spiral blade wound around a central stem or shaft that is commonly hollow (hollow-stem
auger). Augers commonly are available in flights (sections) that are connected together to advance the depth
of the borehole.
- the temperature at which a substance will spontaneously
ignite. Autoignition temperature is an indicator of thermal stability for petroleum
- designating or typical of organisms that derive carbon for the
manufacture of cell mass from inorganic carbon (carbon dioxide).
- unicellular microorganisms that exist either as
free-living organisms or as parasites and have a broad range of biochemical, and often pathogenic,
properties. Bacteria can be grouped by form into five general categories: cocci (spherical), bacilli
(rod-shaped), vibrio (curved rod-shaped), spirilla (spiral), and filamentous
- a dust-collection chamber containing numerous permeable
fabric filters through which the exhaust gases pass. Finer particulates entrained in the exhaust gas stream
are collected in the filters for subsequent treatment/disposal.
- a valve regulated by the position of a free-floating ball that
moves in response to fluid or mechanical pressure.
- a colloidal clay, largely made up of the mineral sodium
montmorillonite, a hydrated aluminum silicate. Because of its expansive property, bentonite is commonly used
to provide a tight seal around a well casing.
- a sloped wall or embankment (typically constructed of
earth, hay bales, or timber framing) used to prevent inflow or outflow of material into/from an
- a method used to determine the toxicity of specific chemical
contaminants. A number of individuals of a sensitive species are placed in water containing specific
concentrations of the contaminant for a specified period of time.
- the introduction of cultured microorganisms into the
subsurface environment for the purpose of enhancing bioremediation of organic contaminants. Generally the
microorganisms are selected for their ability to degrade the organic compounds present at the remediation
site. The culture can be either an isolated genus or a mix of more than one genera. Nutrients are usually
also blended with the aqueous solution containing the microbes to serve as a carrier and dispersant. The
liquid is introduced into the subsurface under natural conditions (gravity fed) or injected under
- the availability of a compound for biodegradation,
influenced by the compound's location relative to microorganisms and its ability to dissolve in
- a substance capable of destroying (killing) living
Biodegradability (or biodegradation
potential) - the relative ease with which petroleum hydrocarbons will degrade
as the result of biological metabolism. Although virtually all petroleum hydrocarbons are biodegradable,
biodegradability is highly variable and dependent somewhat on the type of hydrocarbon. In general,
biodegradability increases with increasing solubility; solubility is inversely proportional to molecular
- a process by which microbial organisms transform or alter
(through metabolic or enzymatic action) the structure of chemicals introduced into the
Biomass - the amount of living matter in a given area or
- the temperature at which a component's vapor pressure
equals atmospheric pressure. Boiling point is a relative indicator of volatility and generally increases with
increasing molecular weight.
- "British Thermal Unit"; the quantity of heat required to
raise the temperature of one pound of water one degree Fahrenheit at 39 degrees F; used as the standard for
the comparison of heating values of fuels.
- the maximum radial distance away from a biosparging well
where the effects of sparging are observable. Analogous to radius of influence of an air sparging
- the amount of mass of a soil per unit volume of soil;
where mass is measured after all water has been extracted and total volume includes the volume of the soil
itself and the volume of air space (voids) between the soil grains.
- a shut-off valve usually found in larger pipe sizes (4
inches or greater). This type of valve can be used for non-critical flow
- the zone of a porous medium above the water table within
which the porous medium is saturated by water under pressure that is less than atmospheric
- the process whereby water rises above the water table into
the void spaces of a soil due to tension between the water and soil
- an off-gas posttreatment unit for control of organic compounds.
Gas enters the unit and passes over a support material coated with a catalyst (commonly a noble metal such as
platinum or rhodium) that promotes oxidation of the organics. Catalytic oxidizers can also be very effective
in controlling odors. High moisture content and the presence of chlorine or sulfur compounds can adversely
affect the performance of the catalytic oxidizer.
- organisms that obtain energy from oxidation or reduction
of inorganic or organic matter.
Coefficient Of Permeability
- see hydraulic
- the simultaneous metabolism of two compounds, in which the
degradation of the second compound (the secondary substrate) depends on the presence of the first compound
(the primary substrate). For example, in the process of degrading methane, some bacteria can degrade
hazardous chlorinated solvents that they would otherwise be unable to attack.
- a reaction in which a metal ion and one or more anionic
ligands chemically bond. Complexes often prevent the precipitation of metals.
- the liquid that separates from a vapor during
- a coefficient of proportionality describing the rate at
which a fluid (e.g., water
or gas) can move through a permeable medium. Conductivity is a function of both the intrinsic permeability of
the porous medium and the kinematic viscosity of the fluid which flows through
Cone Of Depression
- the area around a discharging well where the hydraulic
head (potentiometric surface) in the aquifer has been lowered by pumping. In an unconfined aquifer, the cone
of depression is a cone-shaped depression in the water table where the media has actually been
- a fully saturated aquifer overlain by a confining layer. The
potentiometric surface (hydraulic head) of the water in a confined aquifer is at an elevation that is equal
to or higher than the base of the overlying confining layer. Discharging wells in a confined aquifer lower
the potentiometric surface which forms a cone of depression, but the saturated media is not
- a geologic formation characterized by low permeability that
inhibits the flow of water (see also aquitard).
- (a) in the case of a contaminant, one that does not
degrade and the movement of which is not retarded; is unreactive. (b) in the case of an assumption, one that
leads to a worst-case scenario, one that is most protective of human health and the
- an essential part or component of a system or group (e.g., an
ingredient of a chemical mixture). For instance, benzene is one constituent of
- a type of separator for removal of larger particles from
an exhaust gas stream. Gas laden with particulates enters the cyclone and is directed to flow in a spiral
causing the entrained particulates to fall out and collect at the bottom. The gas exits near the top of the
Darcy's Law: an empirical relationship between hydraulic gradient and
the viscous flow of water in the saturated zone of a porous medium under conditions of laminar flow. The flux
of vapors through the voids of the vadose zone can be related to a pressure gradient through the air
permeability by Darcy's Law.
Potential: the degree to which a substance is likely to be reduced to
a simpler form by bacterial activity.
Denitrification - bacterial reduction of nitrite to gaseous nitrogen under
- the amount of mass per unit
- the process by which molecules in a single phase equilibrate to
a zero concentration gradient by random molecular motion (Brownian motion). The flux of molecules is from
regions of high concentration to low concentration and is governed by Fick's Second
- the process by which a substance or chemical spreads and dilutes
in flowing groundwater or soil gas.
- dissolving of a substance in a liquid solvent
- in the direction of decreasing static head
- lowering the water table due to withdrawal of groundwater as
from a well.
- a measure of a fluid's resistance to tangential or shear
- the amount of interconnected pore space in a soil or rock
through which fluids can pass, expressed as a percent of bulk volume. Some of the voids and pores in a rock
or soil will be filled with static fluid or other material, so that effective porosity is always less than
- something that flows out, especially a liquid or gaseous
- a chemical entity that accepts electrons transferred to it from
another compound. It is an oxidizing agent that, by virtue of its accepting electrons, is itself reduced in
the process. See also terminal electron acceptor and oxidation-reduction.
- a chemical entity that donates electrons to another
compound. It is a reducing agent that, by virtue of its donating electrons, is itself oxidized in the
process. (see also electron acceptor and oxidation-reduction.)
- relying upon or gained from experiment or
- particulates or vapor transported along with flowing gas or
- (a) any of numerous proteins or conjugated proteins
produced by living organisms and functioning as biochemical catalysts. (b) a protein that a living organism
uses in the process of degrading a specific compound. The protein serves as a catalyst in the compound's
- an organism having one or more cells with well-defined
- the process by which a liquid enters the vapor (gas)
- moved from its original place; excavated; removed or
recovered from the subsurface.
- a well employed to extract fluids (either water, gas, free
product, or a combination of these) from the subsurface. Extraction is usually accomplished by either a pump
located within the well or suction created by a vacuum pump at the ground surface.
- microorganisms that can grow in either the presence or the
absence of molecular oxygen. In the absence of oxygen these microorganism can utilize another compound (e.g.,
sulfate or nitrate) as a terminal electron acceptor.
- used to describe organisms that are able to grow in either
the presence or absence of a specific environmental factor (e.g., oxygen). See also facultative
Fick's First Law
- an equation describing the rate at which a gas transfers
into solution. The change in concentration of gas in solution is proportional to the product of an overall
mass transfer coefficient and the concentration gradient.
Fick's Second Law
- an equation relating the change of concentration with time
due to diffusion to the change in concentration gradient with distance from the source of
- the maximum amount of water that a soil can retain after excess
water from saturated conditions has been drained by the force of gravity.
- a calibrated flow measuring device made for a specific
range of flow velocities and fluids.
- the rate of movement of mass through a unit
cross-sectional area per unit time in response to a concentration gradient or some advective
- a petroleum hydrocarbon in the liquid ("free" or non-aqueous)
phase (see also non-aqueous phase liquid, NAPL).
- easily crumbled, not cohesive or
- aerobic, multicellular, nonphotosynthetic, heterotrophic
microorganisms. The fungi include mushrooms, yeast, molds, and smuts. Most fungi are saprophytes, obtaining
their nourishment from dead organic matter. Along with bacteria, fungi are the principal organisms
responsible for the decomposition of carbon in the biosphere. Fungi have two ecological advantages over
bacteria: (1) they can grow in low moisture areas, and (2) they can grow in low pH
- a valve regulated by the position of a circular
- a type of stemmed valve that is used for flow control. The
valve has a globe shaped plug that rises or falls vertically when the stem handwheel is
- the rate of change in value of a physical or chemical parameter
per unit change in position. For example, hydraulic gradient is equal to the difference in head measured at
two points (usually wells) divided by the distance separating the two points. The dimensions of head and
distance are both lengths, therefore the gradient is expressed as a dimensionless ratio
- the water contained in the pore spaces of saturated geologic
- a watery mixture of cement (and commonly bentonite)
without aggregate that is used to seal the annular space around well casings to prevent infiltration of water
or short-circuiting of vapor flow.
- the quantity of energy that must be supplied to raise the
temperature of a substance. For contaminated soils heat capacity is the quantity of energy that must be added
to the soil to volatilize organic components. The typical range of heat capacity of soils is relatively
narrow, therefore variations are not likely to have a major impact on application of a thermal desorption
Henry's Law Constant
- the ratio of the concentration of a compound in air (or vapor)
to the concentration of the compound in water under equilibrium conditions.
- the relationship between the partial pressure of a compound and
the equilibrium concentration in the liquid through a proportionality constant known as the Henry's law
- varying in structure or composition at different locations
- designating or typical of organisms that derive carbon for the
manufacture of cell mass from organic matter.
- uniform in structure or composition at all locations in
- a twist-type connector used for connecting a small
diameter hose to a valve or faucet.
- a coefficient of proportionality describing the rate at which
water can move through a permeable medium. Hydraulic conductivity is a function of both the intrinsic
permeability of the porous medium and the kinematic viscosity of the water which flows through it. Also
referred to as the coefficient of permeability.
- the change in total potentiometric (or piezometric) head between
two points divided by the horizontal distance separating the two points.
- chemical compounds composed only of carbon and
- H(2)O(2). Hydrogen peroxide is used to increase the
dissolved oxygen content of groundwater to stimulate aerobic biodegradation of organic contaminants. Hydrogen
peroxide is infinitely soluble in water, but rapidly dissociates to form a molecule of water [H(2)O] and
one-half molecule of oxygen [O]. Dissolved oxygen concentrations of greater than 1,000 mg/L are possible
using hydrogen peroxide, but high levels of D.O. can be toxic to
Hydrophilic: having an affinity for water, or capable of dissolving in
water; soluble or miscible in water.
- tending not to combine with water, or incapable of dissolving in
water; insoluble or immiscible in water. A property exhibited by non-polar organic compounds, including the
- a condition of low oxygen concentration, below that
- in its original place; unmoved; unexcavated; remaining in
- a flow measurement device for liquids and gases that uses a flow
tube and specialized float. The float device is supported by the flowing fluid in the clear glass or plastic
flow tube. The vertical scaled flow tube is calibrated for the desired flow
- living or occurring naturally in a specific area or environment;
- an engineered structure that facilitates infiltration of
water into the subsurface. Infiltration galleries may consist of one or more horizontal or vertical
perforated pipes, a single gravel-filled trench or a network of such trenches, or a combination of
- the downward movement of water through a soil in response
to gravity and capillary suction.
- a well used to inject under pressure a fluid (liquid or
gas) into the subsurface.
- a well through which a fluid (liquid or gas) is allowed to enter
the subsurface under natural pressure.
- to implant microorganisms onto or into a culture
- between the individual grains in a rock or
- a measure of the relative ease with which a permeable medium can
transmit a fluid (liquid or gas). Intrinsic permeability is a property only of the medium and is independent
of the nature of the fluid.
- the condition in which hydraulic properties of an aquifer
are equal when measured in any direction.
- the ratio of dynamic viscosity to mass density. Kinematic
viscosity is a measure of a fluid's resistance to gravity flow: the lower the kinematic viscosity, the easier
and faster the fluid will flow.
KOW - see octanol/water partition
Liquid Limit (LL)
- the lower limit for viscous flow of a
Liquidity Index (LI)
- quantitative value used to assess whether a soil will
behave as a brittle solid, semisolid, plastic, or liquid. LI is equal to the difference between the natural
moisture content of the soil and the plastic limit (PL) divided by the plasticity index
- the gross physical character of a rock or rock types in a
Lower Explosive Limit (LEL)
- the concentration of a gas below which the concentration
of vapors is insufficient to support an explosion. LELs for most organics are generally 1 to 5 percent by
- a sensitive differential pressure or vacuum gauge
manufactured by Dwyer Instrument Co. that uses a precision diaphragm to measure pressure differences. This
gauge is manufactured in specific pressure or vacuum ranges such as 0 to 2 inches of water column. Magnehelic
gauges are typically used to measure SVE system vacuums.
- a pipe with several apertures for making multiple
- an instrument for measuring fluid pressure. Typically a U-shaped
tube in which opposing fluid pressures reach an equilibrium. The pressure is equal to the differences in the
levels of the fluid on either side of the tube.
- a term that encompasses all of the diverse reactions by which a
cell processes food material to obtain energy and the compounds from which new cell components are
- referring to the formation of methane by certain anaerobic
bacteria during the process of anaerobic fermentation.
- obligate aerobes that function best under conditions of low
- a diminutive, representative system analogous to a larger
system in composition, development, or configuration. As used in biodegradation treatability studies,
microcosms are typically constructed in glass bottles or jars.
- microscopic organisms including bacteria, protozoans, yeast,
fungi, mold, viruses, and algae.
- the release of inorganic chemicals from organic matter in
the process of aerobic or anaerobic decay.
- the amount of water lost from a soil upon drying to a constant
weight, expressed as the weight per unit weight of dry soil or as the volume of water per unit bulk volume of
the soil. For a fully saturated medium, moisture content equals the porosity.
- process whereby molecules of various gases tend to
intermingle and eventually become uniformly dispersed.
- the amount of mass in one mole of molecules of a substance
as determined by summing the masses of the individual atoms which make up the
- aromatic hydrocarbons containing a single benzene
Non-Aqueous Phase Liquid (NAPL)
- contaminants that remain as the original bulk liquid in the
subsurface (see also free product).
- major elements (e.g., nitrogen and phosphorus) and trace elements
(including sulfur, potassium, calcium, and magnesium) that are essential for the growth of
- organisms that require the presence of molecular oxygen
([O(2)] for their metabolism.
- organisms for which the presence of molecular oxygen is
toxic. These organisms derive the oxygen needed for cell synthesis from chemical
Occlude - to cause to become obstructed or closed and thus prevent passage
either into or from.
Octanol/Water Partition Coefficient
(KOW) - a coefficient representing the ratio of the solubility of a
compound in octanol (a non-polar solvent) to its solubility in water (a polar solvent). The higher the Kow,
the more non-polar the compound. Log Kow is generally used as a relative indicator of the tendency of an
organic compound to adsorb to soil. Log Kow values are generally inversely related to aqueous solubility and
directly proportional to molecular weight.
Off-Gas Treatment System
- refers to the unit operations used to treat (i.e.
condense, collect, or destroy) contaminants in the purge gas from the thermal
- see alkenes.
- a flow measurement device for liquids or gases that uses a
restrictive orifice plate consisting of a machined hole that produces a jet effect. Typically the orifice
meter consists of a thin plate with a square edged, concentric, and circular orifice. The pressure drop of
the jet effect across the orifice is proportional to the flow rate. The pressure drop can be measured with a
manometer or differential pressure gauge.
- a chemical reaction consisting of an oxidation reaction in which
a substance loses or donates electrons, and a reduction reaction in which a substance gains or accepts
electrons. Redox reactions are always coupled because free electrons cannot exist in solution and electrons
must be conserved.
- see alkanes.
- the portion of total vapor pressure in a system due to one or
more constituents in the vapor mixture.
- a qualitative description of the relative ease with which
rock, soil, or sediment will transmit a fluid (liquid or gas). Often used as a synonym for hydraulic
conductivity or coefficient of permeability.
- a measure of the acidity of a solution. pH is equal to the
negative logarithm of the concentration of hydrogen ions in a solution. A pH of 7 is neutral. Values less
than 7 are acidic, and values greater than 7 are basic.
- organisms that use light to generate energy (by
photosynthesis) for cellular activity, growth, and reproduction.
- operation of a small-scale version of a larger system to gain
information relating to the anticipated performance of the larger system. Pilot test results are typically
used to design and optimize the larger system.
- a device used to measure the total pressure of a fluid stream
that is essentially a tube attached to a manometer at one end and pointed upstream at the
Plastic Limit (PL)
- the lower limit of the plastic state of a
- one that will deform without shearing (typically silts or
clays). Plasticity characteristics are measured using a set of parameters known as Atterberg
Plasticity Index (PI)
- the range of water content in which soil is in a plastic
state. PI is calculated as the difference between the percent liquid limit and percent plastic
- aromatic hydrocarbons containing more than one fused
benzene ring. Polyaromatic hydrocarbons are commonly designated PAH.
Polynuclear Aromatic Hydrocarbon
- synonymous with polyaromatic hydrocarbon. Designated
- (1) the total volume of pore space in a given volume of
rock or sediment. Pore volume usually relates to the volume of air or water that must be moved through
contaminated material in order to flush the contaminants. (2) the volume of water (or air) that will
completely fill all of the void space in a given volume of porous matrix. Pore volume is equivalent to the
total porosity. The rate of decrease in the concentration of contaminants in a given volume of contaminated
porous media is directly proportional to the number of pore volumes that can be exchanged (circulated)
through the same given volume of porous media.
- the volume fraction of a rock or unconsolidated sediment not
occupied by solid material but usually occupied by water and/or air.
- a pressure differential in a given medium
(e.g., water or air) which
tends to induce movement from areas of higher pressure to areas of lower
- a cellular organism in which the nucleus has no limiting
- single-celled, eucaryotic microorganisms without cell walls.
Most protozoa are free-living although many are parasitic. The majority of protozoa are aerobic or
facultatively anaerobic heterotrophs.
PSI (pounds per square inch)
- a unit of pressure or pressure drop across a flow resistance.
One psi is equivalent to the pressure exerted by 2.31 feet of water column.
PSIG (pounds per square inch
(gauge) - 0 psig = 14.696 psia (psi absolute) = 1.0
- a chamber in which water and soil are mixed together.
Typically mixing is aided by an internal mechanical stirring/kneading
Radius Of Influence
- the maximum distance away from an air injection or extraction
source that is significantly affected by a change in pressure and induced movement of
Reagent - a substance or solution used in a chemical reaction, especially
those used in laboratory work to detect, measure, or produce other
- unreactive, nondegradable;
Redox - short for oxidation-reduction.
- a measure of the ability of a substance to be biodegraded
by bacterial activity. The lower the refractory index, the greater the
- preferential retention of contaminant movement in the
subsurface resulting from adsorptive processes or solubility
- the zone in which all the voids in the rock or soil are filled
with water at greater than atmospheric pressure. The water table is the top of the saturated zone in an
- a groundwater monitoring well situated between a sensitive
receptor downgradient and the source of a contaminant plume upgradient. Contamination should be first
detected in the sentinel well which serves as a warning that contamination may be moving closer to the
receptor. The sentinel well should be located far enough upgradient of the receptor to allow enough time
before the contamination arrives at the receptor to initiate other measures to prevent contamination from
reaching the receptor, or in the case of a supply well, provide for an alternative water
- a special fitting used to seal vials (a liner for a
threaded cap) or gas chromatographs (GCs) to provide closure. Septas can be manufactured in single, double,
or triple layers of silicone rubber and other plastic materials. A syringe with a measured quantity of
contaminant can be injected through a septa closure and into a GC column for separation
- to undergo sequestration.
- the inhibition or stoppage of normal ion behavior by combination
with added materials, especially the prevention of metallic ion precipitation from solution by formation of a
coordination complex with a phosphate.
SESOIL - a one-dimensional model for estimating pollutant distribution in
an unsaturated soil column. SESOIL results are commonly used to estimate the source term for groundwater
transport modeling of the saturated zone.
- the entry of ambient air into an extraction well (used for SVE
and bioventing) without first passing through the contaminated zone. Short circuiting may occur through
utility trenches, incoherent well or surface seals, or layers of high permeability geologic
- the water contained in the pore spaces in the unsaturated
- the amount of mass of a compound that will dissolve in a
unit volume of solution.
- gas-tight canisters typically filled with activated carbon
(charcoal) for collection and transport of vapor samples. In the laboratory the vapors are desorbed and
analyzed to identify the organic compounds and quantify their concentration.
- glass tubes filled with a sorbent material that reacts
chemically with specific organic compounds. Based on the nature of the sorbent and the extent of the chemical
reaction, organic compounds can be identified and their concentration
- a general term used to encompass the processes of absorption,
adsorption, ion exchange, and chemisorption.
Sparge - injection of air below the water table to strip dissolved
volatile organic compounds and/or oxygenate the groundwater to facilitate aerobic biodegradation of organic
- the dimensionless ratio of the density of a substance with
respect to the density of water. The specific gravity of water is equal to 1.0 by definition. Most petroleum
products have a specific gravity less than 1.0, generally between 0.6 and 0.9. As such, they will float on
water--these are also referred to as LNAPLs, or light non-aqueous phase liquids. Substances with a specific
gravity greater than 1.0 will sink through water--these are referred to as DNAPLs, or dense non-aqueous phase
- the limit at which a soil loses its ability to adhere to a metal
- layering or bedding of geologic materials (e.g., rock or
Stratum - a horizontal layer of geologic material of similar composition,
especially one of several parallel layers arranged one on top of another.
- a pit or depression where liquids drain, collect, or are
- gas-tight bags constructed of non-reactive material (Tedlar) for
the collection and transport of gas/vapor samples.
Terminal Electron Acceptor (TEA)
- a compound or molecule that accepts an electron (is
reduced) during metabolism (oxidation) of a carbon source. Under aerobic conditions molecular oxygen is the
terminal electron acceptor. Under anaerobic conditions a variety of terminal electron acceptors may be used.
In order of decreasing redox potential, these TEAs include nitrate, manganic manganese, ferric iron, sulfate,
and carbon dioxide. Microorganisms preferentially utilize electron acceptors that provide the maximum free
energy during respiration. Of the common terminal electron acceptors listed above, oxygen has the highest
redox potential and provides the most free energy during electron transfer.
- describes the primary treatment unit that heats
petroleum-contaminated materials and desorbs the organic materials into a purge gas or
Thermal Desorption System
- refers to a thermal desorber and associated systems for handling
materials and treated soils and treating offgases and residuals.
Total Petroleum Hydrocarbons (TPH)
- a measure of the concentration or mass of petroleum hydrocarbon
constituents present in a given amount of air, soil, or water. The term total is a misnomer, in that few, if
any, of the procedures for quantifying hydrocarbons are capable of measuring all fractions of petroleum
hydrocarbons present in the sample. Volatile hydrocarbons are usually lost in the process and not quantified.
Additionally, some non-petroleum hydrocarbons may be included in the
Total Recoverable Petroleum Hydrocarbons
(TRPH) - an EPA method (418.1) for measuring total petroleum hydrocarbons
in samples of soil or water. Hydrocarbons are extracted from the sample using a chlorofluorocarbon solvent
(typically Freon-113) and quantified by infrared spectrophotometry. The method specifies that the extract be
passed through silica gel to remove the non-petroleum fraction of the
- the time it takes a contaminant to travel from the source to a
particular point downgradient.
- Salts with P(3)O(10)[-5 charge] anion. Most common is sodium
- a rotor designed to convert fluid energy into rotational energy.
Hydraulic turbines are used to extract energy from water as the water velocity increases due to a change in
head or kinetic energy at the expense of the potential energy as the water flows from a higher elevation to a
lower elevation. The fluid velocity tangential component contributes to the rotation of the rotor in a
- an aquifer in which there are no confining beds between the
capillary fringe and land surface, and where the top of the saturated zone (the water table) is at
- the characteristic of a carbon atom in a hydrocarbon molecule
that shares a double bond with another carbon atom.
- the zone between land surface and the capillary fringe
within which the moisture content is less than saturation and pressure is less than atmospheric. Soil pore
spaces also typically contain air or other gases. The capillary fringe is not included in the unsaturated
- it the direction of increasing potentiometric
Vacuum Draft Tube
- a narrow tube lowered into an extraction well through which a
strong vacuum is pulled via a suction pump at ground surface. Fluids (gas, water, and/or free product) are
drawn into the draft tube and conveyed to the surface for treatment or disposal. Depending upon the
configuration of the extraction system, the inlet of the draft tube may be either above or below the static
level of the liquid in the well.
- the zone between land surface and the water table within
which the moisture content is less than saturation (except in the capillary fringe) and pressure is less than
atmospheric. Soil pore spaces also typically contain air or other gases. The capillary fringe is included in
the vadose zone.
- the amount of mass of a vapor per unit volume of the
- the force per unit area exerted by a vapor in an
equilibrium state with its pure solid, liquid, or solution at a given temperature. Vapor pressure is a
measure of a substance's propensity to evaporate. Vapor pressure increases exponentially with an increase in
- a short tube with a constricted throat for determining
fluid pressures and velocities by measuring differential pressures generated at the throat as a fluid
traverses the tube.
- a measure of the internal friction of a fluid that
provides resistance to shear within the fluid. The greater the forces of internal friction (i.e. the greater
the viscosity), the less easily the fluid will flow.
- the process of transfer of a chemical from the aqueous or
liquid phase to the gas phase. Solubility, molecular weight, and vapor pressure of the liquid and the nature
of the gas-liquid interface affect the rate of volatilization.
- the water surface in an unconfined aquifer at which the
fluid pressure in the pore spaces is at atmospheric pressure.
- the process during which a complex compound is reduced to
its simpler component parts, transported via physical processes, or biodegraded over
- the area immediately surrounding the top of a well, or the
top of the well casing.
Windrow - a low, elongated row of material left uncovered to dry.
Windrows are typically arranged in parallel.